75673-76-6

Basic information

• Product Name: bromo(phenylazoacetaldoximato)(triphenylphosphine)palladium(II)
• CAS NO: 75673-76-6
• Molecular Weight: 610.786
• Mol File: 75673-76-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bromo(phenylazoacetaldoximato)(triphenylphosphine)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bromo(phenylazoacetaldoximato)(triphenylphosphine)palladium(II)(75673-76-6)
• EPA Substance Registry System: bromo(phenylazoacetaldoximato)(triphenylphosphine)palladium(II)(75673-76-6)

Safety Data

• Hazardous Substances Data: 75673-76-6(Hazardous Substances Data)

Upstream product

• 63056-54-2 bis(phenylazoacetaldoximato)palladium(II) 
• 25044-96-6 trans-dichlorobis(triphenylphosphine)palladium(II) 
• 75662-80-5 di-μ-bromo-bis[(α-phenylazoacetaldoximato-N,N'')palladium(II)] 

Relevant articles and documents

Selective Cleavage of the Two Types of Pd-N Bonds in Di-μ-halogeno-bis

Triarylphosphines split the halogen bridge of the title complex and also open the arylazo-oximato chelate ring at the azo-end.In solution an equilibrium exists between the closed-ring and open-ring species.The equilibrium constants are reported.Bidentate phosphine and phosphinoarsine simultaneously split the bridge and cleave the Pd-N(azo) bond.Anhydrous HCl gas protonates the oximato-group with its concomitant displacement by Cl-ion; in effect the Pd-N(oxime) bond is selectively cleaved.