75676-42-5Relevant articles and documents
(2-Fluoroallyl)palladium complexes as intermediates in Pd-catalyzed Tsuji-Trost 2-fluoroallylations: Synthesis and reactivity
Bobrova, Angelina Yu.,Mezentsev, Igor A.,Novikov, Maxim A.,Tomilov, Yury V.
, (2020/06/21)
The first examples of π-(2-fluoroallyl)palladium complexes were synthesized, isolated and characterized including chloride dimers, neutral chloride or cationic triflate complexes bearing PPh3 or SPhos as the ligands. Preliminary reactivity patterns indicating strong dependence of the chemoselectivity on “hardness” of the nucleophile and the ligand type were studied.