75681-36-6

Upstream product

• 1056246-70-8 2-bromo-1-tetralone 
• 100-61-8 N-methylaniline 
• 75681-34-4 N/methyl-N-phenylaminomethyl 2-naphthyl ketone 
• 75681-35-5 2-(N-methylanilino)indan-1-one 

Downstream Products

• 54903-06-9 5,6-dihydro-7-methyl-7H-benzocarbazole 
• 75681-42-4 2-(N-methylanilino)-1-naphthol 
• 20603-70-7 5-methyl-5H-10,11-dihydrobenzocarbazole 
• 75681-39-9 2-phenyl-1,2,2a-3,4,8b-hexahydronaphth<2,1-b>azet-8b-ol 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 90-15-3 α-naphthol 

Relevant academic research and scientific papers

Diastereoselective benzylic arylation of tetralins

"Chemical Equation Presented" X = NMePh, NEt2, NHHex, NHPh, NPhth, NH2 R1 = H, OMe, F, Br; R2 = H, Me; ArH = various Friedel-Crafts protocols for the intermolecular, irans-selective benzylic arylation of tetrali

Light-induced Reactions of 2-(N-Alkyl-N-arylamino)acetophenones and Related Amino-ketones: Formation of 1,3-Diarylazetidin-3-ols

On irradiation in ether, 2-(N-methylanilino)acetophenones, Ar1NMe-CH2COAr2 (Ar1,Ar2=Ph,Ph; Ph,p-MeO-C6H4; Ph,p-Ph-C6H4; p-Cl-C6H4,Ph; p-MeO-C6H4,Ph; and p-Me-C6H4,Ph), underwent type II cyclisation to isomeric 1,3-diarylazetidin-3-ols.A minor photoproduct was one of the two expected type II fission products, the corresponding acetophenone Ar2COMe.The second type II fission product, imine Ar1N=CH2, was not detected, but in three cases a 1,3-diarylimidazolidine, probably derived from this imine, was isolated.Similar results were obtained on irradiation of the related amino-ketones, 2-(N-methylanilino)-2'-acetonaphthone and 2-(N-methylanilino)-1-tetralone.Direct fission of the C-2-N bond occured on irradiation of 2-(N-methylanilino)indan-1-one and 2,2-dimethyl-2-(N-methylanilino)acetophenone. 2-(N-Alkylanilino)acetophenones, PhNR-CH2COPh (R=Et, Me2CH, and PHCH2), yielded complex mixtures on irradiation.