75682-53-0Relevant academic research and scientific papers
REACTIVITE PHOTOCHIMIQUE DES α-AMINOENONES: REACTIONS DE CYCLISATION ET NOUVEAU TYPE DE REACTION DANS LES α-SULFONAMIDOCYCLOHEXENONES
Arnould, J.C.,Cossy, J.,Pete, J.P.
, p. 1585 - 1592 (2007/10/02)
The photochemical behaviour of 2-alkylamino 2-cyclohexenones is very sensitive to the nitrogen substituents. α-Ketoazetidines are produced by irradiation of 2-methanesulfonamido-2-cyclohexenones; however a desulfonation and aryl migration process can complete in the case of 2-arenesulfonamido-2-cyclohexenones.Furthermore divinylamine and photo-Fries rearrangements are the main reactions with 2-anilino 2-cyclohexenone and 2-benzoylamido 2-cyclohexenone respectively.
