75688-29-8Relevant academic research and scientific papers
INSERTION D'ALLENES. VII. SYNTHESE DE COMPLEXES (η4-HETERODIENE)FER TRICARBONYL A PARTIR D'ALLENES
Roustan, J. L.,Guinot, A.,Cadiot, P.
, p. 357 - 366 (2007/10/02)
η4-Hydroxytrimethylenemethane-iron complexes are obtained by protonation of complex anions.They isomerise easily into a mixture of isomeric η4-heterodieneiron tricarbonyl complexes which have been separated.This demonstrates that such complexes are now available starting from allenes, alkyl halides and sodium tetracarbonyl ferrate.
