756898-49-4Relevant academic research and scientific papers
On the mechanism of the puzzling "endocyclic" skeletal rearrangement of 1,6-enynes
Cabello, Noemi,Jimenez-Nunez, Eloisa,Bunuel, Elena,Cardenas, Diego J.,Echavarren, Antonio M.
, p. 4217 - 4223 (2007)
Skeletal rearrangements of simple 1,6-enynes have been studied in order to determine the factors that control the formation of five- or six-membered rings. Simple 1,6-enynes substituted only at C-4 preferentially give six-membered rings on skeletal rearra
Tandem cyclopropanation/ring-closing metathesis of dienynes
Peppers, Brian P.,Diver, Steven T.
, p. 9524 - 9525 (2004)
Certain dienynes give cyclorearrangement by tandem cyclopropanation/ring-closing alkene metathesis, triggered by either a ruthenium carbene or noncarbene ruthenium(II) precatalyst. The process represents a variation of enyne metathesis where presumed cycl
