757-36-8Relevant academic research and scientific papers
1-(Trialkylstannylthioalkyl)silatranes
Sorokin,Stankevich,Kuznetsova,Lopyrev,Voronkov
, p. 560 - 563 (2007/10/03)
Two methods of synthesis of 1-(trialkylstannylthioalkyl)silatranes R3SnS(CH2)nSi(OCH2CH2)3N (n = 1, 2) have been developed. The first method involves transetherification of corresponding trimethoxysilanes with tris(2-hydroxyethyl)amine, and the second is based on reaction of sulfur-containing 1-organylsilatranes of the general formula RS(CH2)nSi(OCH2CH2)3N, where R = H, N≡C, MeCO, EtOC(S), with trialkylalkoxystannanes or hexaethyldistannoxane. Reaction of 1-(triethylstannylthiomethyl)silatrane Et3SnS· CH2Si(OCH2CH2)3N with excess MeI involves cleavage of the Sn-S bond and results in formation of triethyl-iodostannane and dimethyl(1-silatranylmethyl)sulfonium iodide. Antimicrobial activity of the products has been studied.
Trialkyl(alkenylthio)stannanes
Voronkov, M. G.,Dubinskaya, E. I.,Legov, G. N.,Stankevich, O. S.,Protasova, L. E.,et al.
, p. 2031 - 2034 (2007/10/02)
Previously unknown trialkyl(alkenylthio)stannanes were obtained by the interaction of alkenyl thiocyanates with trialkyl(methoxy)stannanes; some of their properties and transformations were studied. - Key words: trialkyl(alkenylthio)stannanes; alkenyl thi
