75730-00-6Relevant academic research and scientific papers
Copper-catalyzed 1,2-addition of nucleophilic silicon to aldehydes: Mechanistic insight and catalytic systems
Kleeberg, Christian,Feldmann, Evgenia,Hartmann, Eduard,Vyas, Devendra J.,Oestreich, Martin
supporting information; experimental part, p. 13538 - 13543 (2012/01/06)
Activation of the Si-B inter-element bond with copper(I) alkoxides produces copper-based silicon nucleophiles that react readily with aldehydes to yield α-silyl alcohols (that is, α-hydroxysilanes) after hydrolysis. Two independent protocols were develope
GENERATION OF THIOALDEHYDES VIA FLUORIDE INDUCED ELIMINATION OF Α-SILYLDISULFIDES
Krafft, Grant A.,Meinke, Peter T.
, p. 1947 - 1950 (2007/10/02)
A mild, efficient and general method for the generation of reactive thioaldehydes from α-silyldisulfides is described.
THE PREPARATION OF α-HYDROXYORGANOSILANES FROM α-BORYLORGANOSILANE INTERMEDIATES
Larson, Gerald L.,Argueelles, Rafael,Rosario, Osvaldo,Sandoval, Sydia
, p. 15 - 24 (2007/10/02)
The generation of α-silyl-α-borylmethane derivatives as intermediates and their oxidation to α-hydroxyorganosilanes is reported.The formation of the intermediate α-silyl-α-borylmethane derivatives is via the type I transfer reaction of organoboranes with either (trimethylsilyl)bromomethyllithium and (phenyldimethylsilyl)chloromethyllithium in THF or in some cases hexane.
