75744-71-7

Usage

Uses

As the provided materials do not specify the exact applications of 2,3,3a,4,4a,5,6,7,8,8a,9,10-Dodecahydro-3aβ,8aα-dimethyl-5-methylene-1-isopropylbenz[f]azulene-4aβ,6β-diol, it is not possible to list its uses based on the given information. However, given its unique structure and properties, it may have potential applications in various industries such as pharmaceuticals, materials science, or chemical research. Further investigation and analysis are needed to determine its specific uses and benefits in these fields.

Upstream product

• 106113-21-7 (3aα,4aα,8aβ)-1-isopropyl-3a,8a-dimethyl-5-methylene-2,3,3a,4,4a,7,8,8a,9,10-decahydro-6H-benzazulen-4a-ol 
• 106113-20-6 1-Isopropyl-3a,6-dimethyl-6-pent-4-ynyl-2,3a,4,6,7,8-hexahydro-3H-azulen-5-one 
• 61050-80-4 1-isopropyl-3a-methyl-2,3,3a,4,7,8-hexahydroazulen-5(6H)-one 
• 106113-23-9 (3aα,4aα,7aS*)-3a-methyl-4a-dimethyl-t-butylsilyloxy-2,3,3a,4,4a,5,6,7-octahydrocyclobuta<1,2:1,4>dicyclopenten-1-one 
• 106130-91-0 1-isopropylidene-3a-methyl-4a-(dimethyl-t-butylsilyloxy)-2,3,3a,4,4a,5,6,7-octahydrocyclobuta<1,2:1,4>dicyclopentene 
• 106113-20-6 (3aα,6S*)-1-isopropyl-3a,6-dimethyl-6-(5-pent-4-ynyl)-2,3,3a,4,7,8-hexahydroazulen-5(6H)-one 
• 106158-42-3 (3aα,6β)-1-isopropyl-6-(5-tri-isopropylsilylpent-4-ynyl)-3a-methyl-2,3,3a,4,7,8-hexahydroazulen-5(6H)-one 
• 106130-93-2 (3aα,6S*)-1-isopropyl-6-(5-tri-isopropylsilylpent-4-ynyl)-3a,6-dimethylazulen-5(6H)-one 

Relevant academic research and scientific papers

Synthetic Radical Chemistry. Total Synthesis of (+/-)-Isoamijiol

A total synthesis of the dolastane diterpene (+/-)-isoamijiol (1), found in the brown seaweed Dictyota linearis, is described.The synthesis, which starts from cyclopentanone, uses just seven carbon-to-carbon bond forming reactions, four of which involve free radical intermediates.The 5,7-ring fused (azulene) portion in (1) was elaborated by an intramolecular -photocycloaddition (17)>-intermolecular reductive coupling (29)>cyclobutane fragmentation (15)>sequence, and the 6-ring in compuond (1) was annulated via intramolecular reductive coupling of the terminal acetylenic ketone intermediate (14) .Oxidation of compound (38), using catalytic selenium dioxide in the presence of t-butyl hydroperoxide, then produced (+/-)-isoamijiol which showed spectral data identical with naturally derived material.

FREE RADICAL REACTIONS IN SYNTHESIS. TOTAL SYNTHESIS OF ISOAMIJIOL.

The dolastane carbon framework present in isoamijiol(1) is elaborated from the enamine(5) using seven carbon-carbon bond forming reactions, four of which involve free radical intermediates.