75744-89-7Relevant academic research and scientific papers
Synthese und Koordinationsverhalten von Selenoalkinylen R-Se-CC-R'
Lang, Heinrich,Keller, Holger,Imhof, Wolfgang,Martin, Sabine
, p. 417 - 422 (2007/10/02)
Synthesis and Coordination Ability of Selenoalkynes R-Se-CC-R' Several synthetic methods for the preparation of selenoalkynes R-Se-CC-R'(1) are discussed. 1 reacts with octacarbonyl dicobalt to yield the η2-?-side-on coordinated alkyne complexes R-Se2-CC-R')Co2(CO)6> (8) which contain a sterically hindered carbon-cobalt tetrahedrane cluster unit.The identity of compounds 1 and 8 is documented by analytical and spectroscopic (IR, MS, 1H-, 77Se-, and 13C-NMR) data as well as by X-ray analysis of C6H5-Se2-CC-C6H5)Co2(CO)6> (8a).
Electrophilic additions to allenes. VII. The role of steric versus electronic effects in the reactions of areneselenenyl halides with allenes
Garratt, Dennis G.,Beaulieu, Pierre L.,Morisset, Veronique M.,Ujjainwalla, Mark
, p. 2745 - 2753 (2007/10/02)
The reactions of benzeneselenenyl chloride, bromide, and 2,4,6-trimethylbenzeneselenenyl bromide with alkyl 1,3-disubstituted allenes in methylene chloride solution have been investigated.While kinetic data are in accord with similar rate determining transition states, exhibiting strong steric effects for all three species, the product distributions show changes in both chemoselectivity and configurational-selectivity in accord with two different types of steric interaction mechanisms during the product determining transition states.A mechanism involving rate limiting formation of alkylideneseleniranium ions and/or alkylideneepiselenuranes, followed by isomerization between the alkylideneseleniranium ions by a path not involving allylic ions, prior to the product determining transition states, is proposed.
