75761-11-4Relevant academic research and scientific papers
EFFECT OF REMOTE HETEROATOM SUBSTITUENTS ON STEREOCHEMISTRY IN 1,2 H MIGRATION TO DIVALENT CARBON. EVIDENCE FOR " NEGATIVE " HYPERCONJUGATION OF CARBENE LONE PAIR
Tomioka, Hideo,Hayashi, Norihiro,Inoue, Noboru,Izawa, Yasuji
, p. 1651 - 1654 (2007/10/02)
Aryloxymethylchlorocarbene generated by photolysis of the corresponding diazirine afforded α-aryloxy-β-chloroalkene.The thermodynamically less stable Z-products are the major isomers and its content becomes dominant as more electron-withdrawing groups are
