75761-25-0Relevant academic research and scientific papers
Polycyclic Fluoro-aromatic Compounds. Part 9. Preparation and Some Reactions of Decafluorofluoranthene
Burdon, James,Gill, Harpal S.,Parsons, Ian W.,Tatlow, John Colin
, p. 1726 - 1730 (2007/10/02)
Fluorinations of fluoranthene with cobalt trifluoride and potassium tetrafluorocobaltate give perfluoroperhydrofluoranthene and perfluorotetradecahydrofluoranthene, respectively.Defluorination of either of these over iron(III) oxide gives decafluorofluoranthene, which is attacked by nucleophiles (OMe-, H-, NH2NH2) at position 1,and then at 6, 3, and 4.Oxidation of decafluorofluoranthene with nitric acid gives octafluorofluoranthene-2,3-quinone and then heptafluoro-9-oxofluorene-1-carboxylic acid.
