75795-28-7

Upstream product

• 25541-58-6 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-erythro-hex-2-enopyranoside 
• 151-50-8 potassium cyanide 
• 75795-29-8 methyl 4,6-O-benzylidene-2-cyano-2,3-dideoxy-3-deuterio-β-D-erythro-hex-2-enopyranoside 
• 75795-25-4 (4aR,6R,7S,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-dicarbonitrile 
• 75795-26-5 (4aR,6R,7R,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-dicarbonitrile 
• 53942-05-5 (4aR,6R,8aS)-6-Methoxy-2-phenyl-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxine-7-carbonitrile 
• 75795-27-6 (4aR,6R,7R,8S,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-dicarbonitrile 
• 74-90-8 hydrogen cyanide 

Downstream Products

• 75795-27-6 (4aR,6R,7R,8S,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-dicarbonitrile 
• 75795-26-5 (4aR,6R,7R,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-dicarbonitrile 
• 75795-25-4 (4aR,6R,7S,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-dicarbonitrile 

Relevant academic research and scientific papers

SYNTHESIS, STEREOCHEMISTRY, AND EPIMERIZATION OF METHYL 4,6-O-BENZYLIDENE-2,3-DICYANO-2,3-DIDEOXY-β-D-HEXOPYRANOSIDES HAVING THE allo, altro, gluco, AND manno CONFIRGURATIONS

The reaction of methyl 4,6-O-benzylidene-2,3-dideoxy-3-nitro-β-D-erythro-hex-2-enopyranoside with hydrogen cyanide in the presence of catalytic amounts of potassium cyanide afforded the title compounds.The reaction is shown to involve the probable additio