757950-88-2Relevant academic research and scientific papers
On the phenyliodine(III)-bis(trifluoroacetate)-mediated olefin amidohydroxylation reaction
Tellitu, Imanol,Urrejola, Andrea,Serna, Sonia,Moreno, Isabel,Herrero, M. Teresa,Dominguez, Esther,SanMartin, Raul,Correa, Arkaitz
, p. 437 - 444 (2008/02/03)
When appropriately substituted amides are treated with PIFA in a non-nudeophilic solvent like trifluoroethanol, a stable N-acylnitrenium ion is generated. If under such conditions a C=C double bond is present in the molecule, an intramolecular cyclization
Iodine(III)-mediated aromatic amidation vs olefin amidohydroxylation. The amide N-substituent makes the difference
Serna, Sonia,Tellitu, Imanol,Domínguez, Esther,Moreno, Isabel,Sanmartin, Raúl
, p. 6533 - 6539 (2007/10/03)
A series of N-methoxy- and N-para-methoxyphenylacetamides simultaneously substituted at the α position by a benzyl and an allyl group have been treated with phenyliodine(III)bis(trifluoroacetate) to generate stabilized N-acylnitrenium intermediates. It ha
