75804-36-3

Basic information

• Product Name: 2-Propenoic acid, 2-(phenylseleno)-, methyl ester
• CAS NO: 75804-36-3
• Molecular Formula: C10H10O2Se
• Molecular Weight: 241.148
• Mol File: 75804-36-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-(phenylseleno)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-(phenylseleno)-, methyl ester(75804-36-3)
• EPA Substance Registry System: 2-Propenoic acid, 2-(phenylseleno)-, methyl ester(75804-36-3)

Safety Data

• Hazardous Substances Data: 75804-36-3(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 99484-90-9 3-Chloro-2-phenylselanyl-propionic acid methyl ester 
• 34837-55-3 Phenylselenyl bromide 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 77461-50-8 α-phenylselenoacrylic acid 
• 118893-29-1 diethyl 2-(2-cyclopenten-1-yl)-2-<2-(methoxycarbonyl)-2-(phenylseleno)ethyl>propane-1,3-dioate 
• 78811-38-8 3-Cyclohexyl-2-(phenylseleno)propionsaeure-methylester 

Relevant articles and documents

One-pot facile synthesis of substituted isoindolinones via an Ugi four-component condensation/Diels-Alder cycloaddition/deselenization- aromatization sequence

(Chemical Equation Presented) A versatile one-pot synthesis of substituted isoindolinones from 2-furaldehydes, amines, 2-(phenylselanyl)-acrylic acids, and isocyanides is described. The tandem process involves the Ugi four-component condensation, intramol

A radical cyclization route to pyrrolidines based on conjugate addition to electron deficient phenylselenenylalkenes

α-Phenylselenenyl-α,β-unsaturated esters, amides, ketones, nitriles and sulfones were prepared by zinc chloride promoted chloroselenation/dehydrochlorination of the corresponding α,β-unsaturated compounds. After Michael addition of allyl or propargylamine and triethylborane initiated reductive radical cyclization in the presence of tris(trimethylsilyl)silane, pyrrolidine and dihydropyrrole derivatives, respectively, were obtained. (C) 2000 Elsevier Science Ltd.

Formation of Cis-Fused Cyclopentanoids by Michael Addition and Radical Cyclization

-