75817-27-5Relevant articles and documents
Reaction of Cyclic Aminals with Isocyanates
Parrinello, Giovanni,Muelhaupt, Rolf
, p. 1772 - 1779 (2007/10/02)
The reaction of cyclic aminals with isocyanates gave two different products depending on the substituents and the ring size of the heterocycle.Six-membered aminal rings (hexahydropyrimidines) that contain electron-donating substituents in the 2-position r
RING-CHAIN TAUTOMERISM OF IMIDAZOLIDINE SYSTEM
Witek, Stanislaw,Bielawska, Alicja,Bielawski, Jacek
, p. 1313 - 1317 (2007/10/02)
The existance of the tautomeric equilibrium of imidazolidine system 34has been established.Due to a higher reactivity of NH group in 4, the reaction of the system 34 with PhNCO unbalances the tautomeric equilibrium, and causes an increase in the content of the open-chain urea derivative 6 in the reaction mixture.The use of isocyanates or other similar reagents, e.g., isothiocyanates, seems to be a convenient method for studies of the tautomerism in similar system.