75824-76-9Relevant academic research and scientific papers
Efficient aerobic wacker oxidation of styrenes using palladium bis(isonitrile) catalysts
Naik, Anu,Meina, Liu,Zabel, Manfred,Reiser, Oliver
experimental part, p. 1624 - 1628 (2010/06/17)
The palladium-catalyzed aerobic oxidation of alkenes and especially styrenes (Wacker oxidation) by using chiral pseudo C2-symmetrical bis(isonitrile) ligands in the absence of further cocatalysts gives rise to methyl ketones in a highly chemoselective manner. The palladium bis(isonitrile) catalyst was characterized by NMR spectroscopy and X-ray structure analysis, revealing a dissymmetric coordination of palladium by the two isonitrile moieties.
Synthesis and stereochemistry of hydrogenated 1,1,4,4,7a-pentamethylindenes
Thomas, Alan Francis,Ozainne, Michel,Guntz-Dubini, Renee
, p. 1810 - 1820 (2007/10/02)
Ease of methylation of hydrogenated 2H-inden-2-ones depends on the presence of a double bond in the cyclohexane ring, and occurs readily with compound 20 but not with 10.Differences of reactivity are also noted in Wittig reactions.Most reactions of the sy
