75826-35-6Relevant academic research and scientific papers
Electrochemical cyclization of unsaturated hydroxy compounds. Phenylselenoetherification and phenylselenolactonization
Vukicevic,Konstantinovic,Mihailovic
, p. 859 - 865 (2007/10/02)
Phenylselenoetherification and phenylselenolactonization were performed in one step by electrolysis of unsaturated alcohols or carboxylic acids and diphenyl diselenide in organic solvent containing halide ions as mediators.
Stereoselective Selenolactonization by Superelectrophilic Benzeneselenenyl Triflate
Murata, Shizuaki,Suzuki, Toshiyasu
, p. 849 - 852 (2007/10/02)
Benzeneselenenyl triflate is prepared from benzeneselenenyl chloride and silver trifluoromethanesulfonate.It performs selenium-induced cyclization of β,γ-, γ,δ-, and δ,ε-unsaturated carboxylic acids.
ELECTROCHEMICAL CYCLIZATION OF UNSATURATED HYDROXY COMPOUNDS. PART II. PHENYLSELENOLACTONIZATION
Konstantinovic, S.,Vukicevic, R.,Mihailovic, M. Lj.
, p. 6511 - 6512 (2007/10/02)
Phenylselenolactonization was performed, in one step, by electrolysis of Δ4- and Δ5-unsaturated carboxylic acids and diphenyl diselenide in methanol containing ammonium bromide.
Cyclofunctionalisation of unsaturated acids with benzeneselenenyl chloride. Kinetic and thermodynamic aspects of the rules for ring closure
Clive, Derrick L.J.,Russell, Charles G.,Chittattu, Gim,Singh, Alok
, p. 1399 - 1408 (2007/10/02)
Experimental procedures are described for the synthetically useful reaction by which olefinic acids are converted into lactones carrying a benzeneseleno-group. Data are presented to define some of the mechanistic details of this type of cyclofunctionalisation and kinetic and thermodynamic factors relevant to the Rules for Ring Closure are discussed. A nomenclature is introduced for a treatment of ring-fusion stereochemistry.
