75830-50-1Relevant academic research and scientific papers
Ion Radicals. 46. Reactions of the Adducts of Thianthrene and Phenoxathiin Cation Radicals and Cyclohexene with Nucleophiles
Iwai, Kiyoshi,Shine, Henry J.
, p. 271 - 276 (1981)
Thianthrene cation radical perchlorate 1a reacts with cyclohexene to give an adduct .Reactions of 2a with CN-, C6H5S-, and I- have been studied in dimethyl sulfoxide (Me2SO) and ethanol at room temperature.Reaction of the analogous adduct of cyclohexene and phenoxathiin cation radical perchlorate 2b with I- in ethanol was also studied.The reactions indicate that the adducts have the trans-1,2 structure and undergo facile substitution (SN2) and subsequent elimination (E2) reactions at room temperature.
