75854-88-5

Upstream product

• 108-86-1 bromobenzene 
• 5259-65-4 4-methyl-3-cyclohexen-1-one 
• 70548-79-7 2-methoxy-5-methylphenyl magnesium bromide 
• 75854-87-4 2-methoxy-5-methyl-1,1'-biphenyl 
• 71-43-2 benzene 

Downstream Products

• 75854-89-6 diphenyl-2,4 methyl-4 cyclohexanone 

Relevant academic research and scientific papers

Palladium-catalyzed γ-arylation of β,γ-unsaturated ketones: Application to a one-pot synthesis of tricyclic indolines

(Chemical Equation Presented) Indolines in short order: A catalyst system which allows for efficient γ-arylation of β,γ-unsaturated ketones is described (see scheme; dippf = 1,1′-bis(diisopropylphosphanyl) ferrocene, dba = trans,transdibenzylideneacetone). This method can be applied to a one-pot, two-step synthesis of polycyclic indolines from simple starting materials.

Diprotonation de derives phenoliques. Application a' la preparation de phenyl-3 et de phenyl-4 cyclohexenones

Monocyclic phenols 1-3a (and their methyl ethers) react readily with benzene, in superacid SbF5-HF.In these experiments 4,4 disubstituted cyclohexenones (5, 8 and 11) are the only primary products of the reaction.Their formation is best explain