758695-95-3Relevant academic research and scientific papers
Radical hydrometalation of functional ethylenic compounds: Radical autoinhibition changes the regioselectivity
El Kadib, Abdelkrim,Feddouli, Amal,Riviere, Pierre,Delpech, Fabien,Riviere-Baudet, Monique,Castel, Annie,Ahra, Mohamed,Hasnaoui, Aissa,Burgos, Francisco,Manriquez, Juan M.,Chavez, Ivone
, p. 446 - 454 (2005)
Hydrometalation of carbon-carbon double bonds by group 14 hydrides is inhibited by carbonyl compounds-mainly by α,β-unsaturated carbonyl groups-as efficiently as by classical radical trapping compounds, such as galvinoxyl and hydroquinone. This phenomenon
