75893-98-0Relevant academic research and scientific papers
Ketalization of Dihydroxy Sulfones (8-S-4 Species) by Cyclodehydration To Form Spirobicyclic Oxysulfurane Oxides (10-S-5 Species)
Lam, William Y.,Martin, J. C.
, p. 4462 - 4468 (2007/10/02)
Dihydroxy sulfones 6 and 7 react with the dehydrating agent Ph2S(OC(CF3)2Ph)2 (1) to give sulfurane oxides 8 and 9, respectively.These reactions are thought to be the first examples of direct ketalization of sulfones by dehydration.A possible mechanism fo
Diaryltetraoxypersulfuranes: Preparation, Characterization, and Reactions
Lam, William Y.,Martin, J. C.
, p. 120 - 127 (2007/10/02)
Diarylbis(acyloxy)dialkyloxypersulfurane 7, the first example of hexacoordinate organosulfur(VI) derivative lacking fluorine ligands, a sulfone bisketal, was synthesized by treatment of sulphide diol diacid 6 with pyridine and tert-butyl hypochlorite at 0
