75910-63-3Relevant academic research and scientific papers
Evaluation of Chelation Effects Operative during Diastereoselective Addition of the Allylindium Reagent to 2- And 3-Hydroxycyclohexanones in Aqueous, Organic, and Mixed Solvent Systems
Paquette, Leo A.,Lobben, Paul C.
, p. 5604 - 5616 (1998)
The unprotected 2- and 3-hydroxycyclohexanones 1-8 were prepared by methods that skirted as much as possible their proclivity for α-ketol rearrangement (where the possibility for such isomerization exists). The diastereofacial selectivity of their reactio
Non-stereoselective Vanadium-catalysed Epoxidation of 2-Benzylidenecyclohexanols
Sanghvi, Y. S.,Rao, A. S.
, p. 608 - 610 (2007/10/02)
Vanadyl acetylacetone-t-butyl hydroperoxide epoxidation of allylic alcohols (1-5), which have hydroxy groups allylic to exocyclic double bonds, is non-stereoselective; along with cis-epoxy alcohols (6-10), significant amounts of trans-epoxy alcohols (11-1
