75918-79-5

Usage

Family

Triazole family

Heterocycle

Five-membered ring containing three nitrogen atoms and two carbon atoms

Phenyl groups

Attached to the 1 and 4 positions of the triazole ring

Carbaldehyde group

Attached to the 5 position of the triazole ring

Organic chemistry

Used in the synthesis of various compounds

Pharmaceuticals

Potential use in the development of new drugs

Agrochemicals

Potential use in the development of new pesticides or fertilizers

Materials science

Potential use in the development of new materials

Coordination chemistry

Potential use in the formation of coordination complexes

Building block

Can be used as a starting point for the synthesis of more complex organic molecules

Upstream product

• 2579-22-8 Phenylpropargyl aldehyde 
• 622-37-7 Phenyl azide 
• 15764-89-3 5-(Diazomethyl)-1,4-diphenyl-1,2,3-triazole 
• 75918-91-1 5-(bromomethyl)-1,4-diphenyl-1,2,3-triazole 
• 184292-75-9 [1-(3,5-Diphenyl-3H-[1,2,3]triazol-4-yl)-meth-(E)-ylidene]-phenyl-amine 
• 82671-74-7 N-benzylidene(phenylethynyl)amine 
• 15765-00-1 5-methyl-1,4-diphenyl-1H-1,2,3-triazole 

Downstream Products

• 50640-06-7 1,4-diphenyl-1H-1,2,3-triazole-5-carboxylic acid 
• 184292-75-9 [1-(3,5-Diphenyl-3H-[1,2,3]triazol-4-yl)-meth-(E)-ylidene]-phenyl-amine 
• 13148-78-2 1,4-diphenyl-[1,2,3]-triazole 

Relevant academic research and scientific papers

Cycloaddition of organic azides to α,β-acetylenic aldimines

The reaction selectivity of aryl azides with α,β-acetylenic aldimines R1C≡C-CH=NR2 is independent of R1 and R2: the addition always occurs chemospecifically at the triple bond and results in formation of 1-aryl-

Site of Attack of a Carbene on Alkylbenzenes, Naphthalene, and Thiophene and the Norcaradiene-Cycloheptatriene Equilibration

Upon thermolysis at 40-50 degC, 5-(diazomethyl)-1,4-diphenyl-1,2,3-triazole (1) reacts with p-ethyltoluene, p-cymene, p-tert-butyltoluene, p-diisopropylbenzene, durene, and naphthalene to give a mixture of carbene-derived cycloheptatriene/norcaradiene pro

Reaction of a Triazolylcarbene with the Xylenes and Mesitylene and the Resulting Norcaradiene-Tropilidene Rearrangements

An improved synthesis of 5-(diazomethyl)-1,4-diphenyl-1,2,3-triazole (1) has been developed.It fragments to a carbene at 40-50 deg C and reacts with o-, m-, or p-xylene or indan at 40-50 deg C to give high yields of cycloheptatriene products, presumably t