7596-95-4Relevant academic research and scientific papers
Catalytic kinetics and mechanism transformation of Fe(acac)3 on the urethane reaction of 1,2-propanediol with phenyl isocyanate
Yang, Pengfei,Li, Tianduo,Li, Junying
, p. 623 - 628 (2013)
The urethane reaction of 1,2-propanediol with phenyl isocyanate was investigated with ferric acetylacetonate (Fe(acac)3) as a catalyst. In situ Fourier transform infrared spectroscopy was used to monitor the reaction, and catalytic kinetics of Fe(acac)3 was studied. The reaction rates of both hydroxyl groups were described with a second-order equation, from which the influence of the Fe(acac)3 concentration and reaction temperature was discussed. It was very surprising that the relationship between 1/C and t became constant when reaction temperature increased, which indicated that there was no reactive distinction between the two hydroxyl groups. Although the phenomenon differed with the variation of temperature, it was unaffected by the Fe(acac)3 concentration. It was attributed to the transformation of the reaction mechanism with the increase in temperature. Furthermore, activation energy (Ea), enthalpy (ΔH), and entropy (ΔS) for the catalyzed reaction were determined from Arrhenius and Eyring equations, which testified to the transformation of the reaction mechanism.
REGIOSELECTIVE (PHENYLCARBAMOYL)ATION OF POLYHYDROXY COMPOUNDS BY PHENYL ISOCYANATE-ZINC NAPHTENATE
Nishino, Shigeyoshi,Ishido, Yoshiharu
, p. 161 - 174 (2007/10/02)
In the presence of zinc naphtenate as the catalyst, the reaction of phenyl isocyanate with 1,2-propanediol and 3,4-isopropylidene-D-mannitol gave the primary phenylcarbamates in high yield. 1,2,6-Hexanetriol was selectively phenylcarbamoylated at O-1 and
