75980-62-0Relevant academic research and scientific papers
Photo-curable reparative material for dental use
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, (2008/06/13)
A photocurable dental restorative comprising (i) 100 parts by weight of a polymerizable monomer, (ii) 0.01 to 5 parts by weight of a photopolymerization initiator of acylphosphine oxide, and (iii) 200 to 1900 parts by weight of an inorganic filler, wherein the inorganic filler (iii) is a mixed filler of: (A) irregular-shaped inorganic particles having an average particle size of not smaller than 0.1 μm but smaller than 1 μm; (B) spherical inorganic particles having an average primary particle size of not smaller than 0.1 μm but not larger than 5 μm; and (C) fine inorganic particles having an average primary particle size of not larger than 0.1 μm; which are so blended as to satisfy the following mass ratios {circle over (1)} to {circle over (3)}: mA/(mB+mC)=0.2 to 3??{circle over (1)} mB/(mB+mC)=0.5 to 0.99??{circle over (2)} mC/(mB+mC)=0.01 to 0.5??{circle over (3)} where mA, mB and mC are masses of the inorganic particles (A) to (C). The restorative features excellent handling property, and makes it possible to obtain a cured product having a high fracture toughness and excellently glossy surface.
Preparation of α-carbonylphosphine oxides
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, (2008/06/13)
The preparation of α-carbonylphosphine oxides by oxidizing an α-hydroxyalkyl phosphine oxide with an organic hydroperoxide or of an organic peroxy acid in the presence of a compound of a Group IV to Group VIII metal in the periodic table, and novel α-hydroxybenzyl phosphine oxides. α-Carbonylphosphine oxides are used as photoinitiators for polymerizable compositions.
