75982-94-4

Upstream product

• 12130-66-4 bis(cycloocta-1,5-diene)platinum⁽⁰⁾ 
• 501-65-5 diphenyl acetylene 

Downstream Products

• 111848-25-0 {bis(dicyclohexylphosphino)ethane}(diphenylacetylene)platinum⁽⁰⁾ 
• 69101-79-7 Pt(1,2-bis(diphenylphosphino)ethane)diphenylacetylene 
• 373391-85-6 Pt(1,2-bis(diisopropylphosphino)ethane)(η(2)-diphenylacetylene) 
• 373391-83-4 [Pt{κ²-(P,N)-iPr₂PC₂H₄NMe₂}(η²-diphenylacetylene)] 
• 409319-48-8 Pt((diisopropylphosphinodimethylamino)ethane)2(η(2)-diphenylacetylene) 
• 373391-88-9 (bis(diisopropylphosphino)methane)Pt(PhCCPh) 
• 1020663-57-3 [(1,2-bis((2,4,6-tri-tert-butylphenyl)phosphinidene)cyclobuta[l]phenanthrene)Pt(diphenylacetylene)] 
• 1246030-08-9 [Pt(C₆H₅CCC₆H₅)((C₆H₄OCH₃)2C₄(PC₆H₂(C(CH₃)3)3)2)] 
• 1246030-14-7 [Pt(C₆H₅CCC₆H₅)((C₆H₄CF₃)2C₄(PC₆H₂(C(CH₃)3)3)2)] 

Relevant academic research and scientific papers

Synthesis and structures of platinum diphenylacetylene and dithiolate complexes bearing diphosphinidenecyclobutene ligands (DPCB-Y)

A series of platinum complexes of the type [Pt(D)(A)] having two kinds of π-conjugated ligand systems with donor and acceptor properties are prepared, using p-substituted diphenylacetylenes (tolan-X; X = OMe, H, CF3), 1,2-benzenedithiolato (bdt) and 1,3-dithia-2-thione-4,5-dithiolato (dmit) as π-donor ligands (D), and 1,2-diaryl-3,4-bis[(2,4,6-tri-tert-butylphenyl) phosphinidene]cyclobutenes (DPCB-Y; diaryl = 2C6H4-p-Y (Y = OMe, H, CF3), biphenyl-2,2′-diyl) as π-acceptor ligands (A). The electronic structures of the resulting complexes are examined in detail to investigate π-orbital interaction occurring in DPCB-Y complexes with a low-coordinate phosphorus ligand. The 31P NMR chemical shifts are highly sensitive to the Pt-P distances of the complexes, and linearly correlated with the bond lengths. The UV-vis absorption spectra of [Pt(tolan-X)(DPCB-Y)] display π-π* transitions in the visible region, which are shifted to longer wavelengths as the electron-donating ability of X and electron-withdrawing ability of Y increase, respectively. The complex [Pt(tolan-OMe)(DPCB-CF3)] with a donor-acceptor combination of substituents exhibits particularly low-energy absorption. The absorption is further red-shifted for [Pt(bdt)(DPCB-phen)] and [Pt(dmit)(DPCB-phen)] having dithiolates as strong π-donor ligands.

Synthesis and structures of platinum(0) alkyne complexes with extended π-conjugated systems

1,2-Bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobuta[l]phenanthrene (DPCB-phen) as a low-coordinated phosphorus ligand forms the platinum(0) alkyne complexes [Pt(alkyne)-(DPCB-phen)] with extended π-conjugated systems. The colors of the complexes a