76008-25-8Relevant academic research and scientific papers
REACTIVITY OF PERFLUOROPHENYL-CONTAINING VERDAZYLS. II. DEHYDROGENATION OF THIOPHENOL
Polumbrik, O. M.,Ryabokon', I. G.
, p. 1809 - 1813 (2007/10/02)
The kinetics of the dehydrogenation of thiophenol by perfluorophenyl-containing verdazyls in acetonitrile were studied by UV and ESR spectroscopy.The reaction rate depends substantially on the position and the number of perfluorophenyl substituents in the radical.The dependence of the activation energies on the thermal effects of the reactions is described by the Polanyi-Semenov equation.
DONOR-ACCEPTOR CHARACTERISTICS OF PENTAFLUOROPHENYL-CONTAINING VERDAZYL RADICALS
Polumbrik, O. M.,Ryabokon', I. G.,Vasil'kevich, N. G.,Igant'ev, N. V.,Markovskii, L. N.
, p. 167 - 173 (2007/10/02)
The oxidation and reduction potentials of pentafluorophenyl-containing verdazyl radicals were determited by polarografy at a dropping mercury and a rotating platinum electrode; the electrochemical reactions of these radicals take place reversibly with the
