76014-98-7Relevant academic research and scientific papers
Organoboranes. 38. A Facile and Highly Efficient Addition of B-1-Alkynyl-9-borabicyclononanes to Aldehydes and Ketones: An Exceptionally Chemoselective Synthesis of Propargylic Alcohols
Brown, Herbert C.,Molander, Gary A.,Singh, Shankar M.,Racherla, Uday S.
, p. 1577 - 1582 (1985)
B-1-Alkynyl-9-borabicyclononanes (B-1-alkynyl-9-BBN) readily undergo addition to aldehydes and ketones and afford the propargylic alcohols in very high isolated yields.Unlike many other alkynyl metals (RCCM, M = Li, Na, K, Mg, Zn, and Al), which
