76024-95-8

Basic information

• Product Name: 5-nitro-5-(phenylsulfonyl)nonane
• CAS NO: 76024-95-8
• Molecular Weight: 313.418
• Mol File: 76024-95-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-nitro-5-(phenylsulfonyl)nonane(CAS DataBase Reference)
• NIST Chemistry Reference: 5-nitro-5-(phenylsulfonyl)nonane(76024-95-8)
• EPA Substance Registry System: 5-nitro-5-(phenylsulfonyl)nonane(76024-95-8)

Safety Data

• Hazardous Substances Data: 76024-95-8(Hazardous Substances Data)

Upstream product

• 542-69-8 1-iodo-butane 
• 74737-89-6 phenylsulfonylnitromethane sodium salt 

Relevant articles and documents

α-NITRO SULFONES. 2. CONVENIENT NEW SYNTHESIS AND SELECTED FUNCTIONAL GROUP TRANSFORMATIONS

(Phenylsulfonyl)nitromethane (1) is preferentially C-alkylated by benzylic halides and primary alkyl iodides, affording secondary α-nitro sulfone products. α-Nitro sulfones are also obtained from the corresponding C-alkylation of allylic acetates in the presence of catalytic tetrakis(triphenylphosphine)palladium.The palladium(0)-catalyzed reaction is stereospecific for geranyl and neryl acetates and is also regioselective.Desulfonation of α-nitro sulfones is readily accomplished by light-induced reduction with 1-benzyl-1,4-dihydronicotinamide (BNAH).Reduction of secondary α-nitro sulfones with 20percent aqueous titanium(III) chloride affords nitriles.Oxidation with alkaline permanganate affords carboxylic acids.