76030-63-2Relevant academic research and scientific papers
CHEMISTRY OF A 1,5-DIBLOCKED FLAVIN. 2. PROTON AND ELECTRON TRANSFER STEPS IN THE REACTION OF DIHYDROFLAVINS WITH OXYGEN.
Eberlein,Bruice
, p. 6685 - 6697 (2007/10/02)
The objective of the present investigation has been to clarify certain mechanistic details of the reaction of 1,5-dihydroflavins with O//2 in aqueous solution. Of particular concern has been the role of flavin radical and O//2** minus as intermediates and
Products of the Decomposition of the Anion of a 4a-Hydroperoxyisoalloxazine Hindered in the 9a and 10a Positions
Bruice, Thomas C.,Miller, Audrey
, p. 693 - 694 (2007/10/02)
Products formed from the decomposition of the 4a-peroxy-anion of the flavin (1d) are only accountable through reactions involving the 4a-hydroperoxide anion; kinetic and product studies both argue against the involvement of a 4a -> 10a peroxy-anion migration.
