76043-12-4

Upstream product

• 76042-33-6 2-[1-(1-Phenylsulfanyl-cyclopropyl)-meth-(E)-ylidene]-cyclohexanol 
• 76042-27-8 2-<(1-((2,6-dimethoxyphenyl)thio)cyclopropyl)methylene>cyclohexanol 
• 76043-01-1 2-[Hydroxy-(1-phenylsulfanyl-cyclopropyl)-methyl]-cyclohexanone 
• 76043-05-5 (E)-2-<<1-(phenylthio)cyclopropyl>methylene>cyclohexanone 
• 76042-18-7 2-<(1-((2,6-dimethoxyphenyl)thio)cyclopropyl)hydroxymethyl>cyclohexanone 
• 76042-22-3 (E)-2-<(1-((2,6-dimethoxyphenyl)thio)cyclopropyl)methylene>cyclohexanone 
• 108-94-1 cyclohexanone 
• 124708-58-3 cyclohexene-1-yl(1-methxycycloprop-1-yl)methanol 

Downstream Products

• 76042-53-0 (Z)-2-(1-cyclohexenyl)-1-((carbomethoxy)methyl)cyclobutanol 
• 76042-53-0 (E)-2-(1-cyclohexenyl)-1-((carbomethoxy)methyl)cyclobutanol 
• 76042-42-7 trans-2-(1-cyclohexenyl)cyclobutanol 
• 76042-42-7 (Z)-2-(1-cyclohexenyl)cyclobutanol 
• 76042-65-4 (Z)-2-(4-oxohexylidene)cyclohexanol 
• 76042-66-5 (E)-2-(4-oxohexylidene)cyclohexanol 
• 76042-73-4 (Z)-2-(4-oxo-5-(carbomethoxy)pentylidene)cyclohexanol 
• 76042-74-5 (E)-2-(4-oxo-5-(carbomethoxy)pentylidene)cyclohexanol 

Relevant academic research and scientific papers

EFFICIENT SYNTHESYS OF 2-VINYLCYCLOBUTANONES BY THE REARRANGEMENT OF 1-METHOXY-1-CYCLOPROPYLCARBINOLS UNDER NEUTRAL CONDITIONS

A common synthesis of cyclobutanones involves the rearrangement of 1-alkoxy- or 1-(phenylthio)cyclopropylcarbinols under acidic conditions.We report that the synthetically useful 2-vinylcyclobutanones can be prepared in good yield in the absence of proton

A SYNTHESIS OF 2-VINYLCYCLOBUTANONES USING 1-METHOXYCYCLOPROYLLITHIUM REAGENTS

A facile synthesis of 2-vinylcyclobutanones consists of reductive lithiation of 1-phenylthio-1-methoxycyclopropanes, addition of enals or enones to the resulting α-lithioethers, and acid catalyzed rearrangement of the allylic alcohols thus produced.