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Cycloaddition of Diazomethane to Unsymmetrical Carbodiimides and Mass Spectroscopy Study of 1,5-Disubstituted 1,2,3-Triazoles
Svetlik, Jan,Lesko, Jan,Martvon, Augustin
, p. 635 - 642 (2007/10/02)
By the reaction of unsymmetrically substituted carbodiimides with diazomethane the corresponding 1,2,3-triazoles have been obtained.The structure of the adducts was elucidated by IR, UV, 1H-NMR and high resolution mass spectrometry. - Keywords: Cycloaddition / Mechanism / Sigmatropic shift / 1,2,3-Triazoles
