760948-50-3Relevant academic research and scientific papers
Acylation of aryl halides and α-bromo acetates with aldehydes enabled by nickel/tbadt cocatalysis
Fan, Pei,Zhang, Chang,Zhang, Linchuan,Wang, Chuan
supporting information, p. 3875 - 3878 (2020/05/14)
In this protocol aryl halides and α-bromo acetates are efficiently cross-coupled with an array of (hetero)aromatic and aliphatic aldehydes under the cooperative catalysis of nickel and tetrabutylammonium decatungstate as a hydrogen-atom-transfer photocatalyst. This method provides a concise approach to a variety of ketones with high compatibility of various functional groups.
Methylsulfonyl and hydroxyl substituents induce Z-stereocontrol in the McMurry olefination reaction
Uddin, Md. Jashim,Rao, P. N. Praveen,Knaus, Edward E.
, p. 1513 - 1516 (2007/10/03)
Aryl ketones possessing methylsulfonyl and hydroxyl substituents, that induce stereocontrol, selectively afford Z-olefins using a Zn-TiCl4 catalyzed McMurry reaction.
