76108-08-2Relevant academic research and scientific papers
Synthesis of N-Aminated Salts of Aliphatic tert-Amines, (Trialkyl)amidines, and (Pentaalkyl)guanidines by Electrophilic Amination in an Ethereal Solvent
Fujita, Hikaru,Arai, Takanari,Kunishima, Munetaka
, p. 85 - 88 (2022/01/31)
The electrophilic amination of nitrogen-based nucleophiles, including strong organic bases, was conducted in an Et2O solvent using O-(mesitylenesulfonyl)hydroxylamine. Aliphatic tert-amines and N,N,N′-(trialkyl)amidines rapidly formed precipita
The Thermolysis of Heterocyclic Aminimines
Posvic, Harvey,Meireles, Jorge C. de
, p. 1241 - 1243 (2007/10/02)
Aminimines derived from six heterocyclic tertiary amines were thermolyzed in t-butyl alcohol at ca. 80 deg.N-Methylindoline gave a good yield of the ring-opened product, and a double elimination on 1,4,4-trimethylpiperidine gave 3,3-dimethyl-1,4-pentadiene.The aminimine derived from quinuclidine was stable to elimination under these conditions.Simple elimination products were not obtained from N-methylpyrrolidine, N-methylpiperidine, or N-methyltetrahydroisoquinoline.
