76124-47-5Relevant academic research and scientific papers
The structural and electrochemical consequences of hydrogenating copper N2S2 Schiff base macrocycles
Trotter, Katherine D.,Taylor, Michelle K.,Forgie, John C.,Reglinski, John,Berlouis, Leonard E.A.,Kennedy, Alan R.,Spickett, Corinne M.,Sowden, Rebecca J.
scheme or table, p. 1529 - 1538 (2010/08/05)
A series of cis and trans tetradentate copper macrocyclic complexes, of ring size 14-16, that employ amine and thioether donor groups are reported. Apart from 5,6,15,16-bisbenzo-8,13-diaza-1,4-dithia-cyclohexadecane copper(I) (cis-[Cu(H4Nb
Substituted diether diols by ring-opening of carbocyclic and stannylene acetals
Martinez-Bernhardt, Rolando,Castro, Peter P.,Godjoian, Gayane,Gutierrez, Carlos G.
, p. 8919 - 8932 (2007/10/03)
Reduction of malonaldehyde bis(ethylene and propylene acetals) with borane or monochloroborane produces diether diols 1 and 2 in high yield. Similar reduction of glyoxal his(ethylene acetals) has only limited utility for the preparation of tetrasubstituted triethylene glycols 3. Organotin chemistry is complementary: stannylene acetals prepared from disubstituted vicinal diols can be alkylated with half an equivalent of 1,2-dibromoethane to produce tetrasubstituted triethylene glycols 3, or with two equivalents of 2-chloroethanol to produce disubstituted triethylene glycols 4.
A Convenient Synthesis of Substituted Polyether Diols
Castro, Peter P.,Tihomirov, Serge,Gutierrez, Carlos G.
, p. 5179 - 5181 (2007/10/02)
Alkyl-substituted polyether diols (or polythioether diols), which are potential precursors to substituted crown ethers, are produced in high yield by the selective reductive cleavage of C-O bonds in bis(cyclic acetals) by borane or monochloroborane.
