761441-54-7Relevant academic research and scientific papers
Preparation method of 4, 5-dicyano-2-trifluoromethyl-imidazolium salt
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Paragraph 0033; 0036-0054, (2021/11/03)
The invention provides a preparation method of 4, 5-dicyano-2-trifluoromethyl-imidazolium salt, and the preparation method comprises the following steps: mixing 4, 5-dicyano-2-trifluoromethyl-imidazole with polybasic acid salt, and carrying out a reaction, so as to obtain the 4, 5-dicyano-2-trifluoromethyl-imidazolium salt. The 4, 5-dicyano-2-trifluoromethyl-imidazolium salt prepared by the preparation method provided by the invention is high in yield and low in water content.
Process for Preparing Lithium Imidazolate Salt and Intermediate Therefor
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Paragraph 0100-0103; 0105; 0106, (2021/02/02)
The present invention relates to a method for preparing lithium imidazolate salts and intermediates used therein. The present invention relates to a method for producing the same. High purity lithium imidazolate salts can be efficiently and economically produced.
Preparation method of 4,5-dicyan base-2-trifluoro-methylimidazole and prepared intermediate and salt thereof
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Paragraph 0058; 0061, (2017/04/12)
The invention belongs to the technical field of chemical synthesis and particularly relates to a preparation method of 4,5-dicyan base-2-trifluoro-methylimidazole and a prepared intermediate and salt thereof. Diaminoaleo dinitrile and trifluoroacetic acid ester are subjected to aminolysis of ester with solvent or without solvent, amide is obtained, the amide is then subjected to intramolecular dehydration, a crude product of the 4,5-dicyan base-2-trifluoro-methylimidazole is obtained, after the crude product is purified, high-purity dehydrate of the 4,5-dicyan base-2-trifluoro-methylimidazole is obtained, then the high-purity dehydrate is mixed with water phase suspension liquid of salt of metal elements and stirred for a reaction, after the reaction is ended, filtering is conducted to remove an undissolved substance, filtrate is evaporated to be dry in a rotary evaporation mode, after dissolution with solvent is conducted again, filtering, rotary evaporation and vacuum drying are conducted, and the high-purity 4,5-dicyan base-2-trifluoro-methylimidazole salt is obtained. The condition of the whole technological process is safer and milder compared with those of other processes for producing the 4,5-dicyan base-2-trifluoro-methylimidazole, and the preparation method meets the requirement for scaled production.
FIVE-MEMBERED CYCLIC ANION USE THEREOF AS AN ELECTROLYTE
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Paragraph 0071; 0072, (2015/11/28)
A pentacyclic anion salt is provided for use thereof in electrolyte compositions. The compound has an inorganic, organic or organometallic cation M of valency m (1≦m≦3) and m anions corresponding to the formula (I) in which Rf is a —CFZ′Z″ group in which Z′ is F or a perflouroalkyl group having from 1 to 3 carbon atoms, and Z″ is an H, F or Cl group, an optionally fluorinated or perfluorinated alkoxy group having from 1 to 5 carbon atoms, an optionally fluorinated or perfluorinated oxaalkoxy group having 1 to 5 carbon atoms or an optionally fluorinated or perfluorinated alkyl group having from 1 to 5 carbon atoms; Z″ being other than F when Z′ is F. An electrolyte composition comprises said salt in solution in a liquid solvent or a polymer solvent.
