76152-10-8Relevant academic research and scientific papers
STUDY OF LIGAND ISOMERIC COMPLEXES OF N-FURFURYLSALICYLALDIMINE
Bhagwat, Urmila A.,Mukhedkar, Vasudha A.,Mukhedkar, Anant J.
, p. 2319 - 2322 (1980)
The ligand isomeric complexes (OC4H3CH2N=CHPhOH, A, and OC4H3CH=NCH2PhOH, B) of N-furfurylsalicylaldimine with CoIII, NiII, CuII, and PdII have been synthesised.The nature of the isomerism was characterised by t
Molecular and intracomplex dioxomolybdenum(VI) compounds with o-hydroxyazomethines, derivatives of salicylaldehydes and 2-furfurylamine: Crystal structures of 3-methoxysalicylidene-2-furfurylamine (HL2) and the binuclear complex [{MoO2(L2)(MeOH)}2(μ-O)]
Sergienko,Abramenko,Gorbunova, Yu. E.,Churakov
, p. 175 - 181 (2017)
The crystal structures of methoxysalicylidene-2-furfurylamine (HL2) and the related binuclear complex [{MoO2(L2)(MeOH)}2(μ-O)] (I) have been determined by single-crystal X-ray diffraction. In complex I, which lies on a crystallographic twofold axis passing through the bridging oxo ligand O(4), the Mo atom has a distorted octahedral coordination (facial isomer) with two terminal oxygen atoms (O(3), O(6)) and the bridging oxo ligand, the O(7) and N(1) atoms of the bidentate chelating ligand (L2)–, and the O(5) atom of the monodentate methoxy ligand. In the HL2 molecule, the intramolecular hydrogen bond O–Н???N closes the six-membered H-ring HOC3N.
Microwave solid phase synthesis, characterization and antimicrobial activities of manganese(II) complex with 2-((furan-3-ylmethylimino)methyl)phenol
Xu, Suo-Ping,Cao, Ting-Ting,Wang, Si-Jia,Miao, Wei-Qing,Wu, Shu-Jie,Zhu, Ya-Nan
, p. 1735 - 1738 (2015)
Mononuclear complex of manganese (1) has been designed and synthesized by 2-((furan-3-ylmethylimino)methyl)phenol (L) with MnCl2·4H2O in microwave radiation. The complex was characterized by X-ray crystallography, confirmi
Catalyst-free direct ring-opening of cyclic aldimines with aliphatic primary amines to construct o-hydroxy schiff bases
Wu, Ziyan,Wang, Jingjing,Li, Feng,Zhai, Hanhui,Ding, Qiuyue,Han, Dongyun,Cao, Zubin
supporting information, (2022/01/28)
We firstly describe a catalyst-free direct ring-opening of cyclic aldimines with abundant aliphatic primary amines to construct o-hydroxy schiff bases under mild reaction conditions. The corresponding products were generated in good to excellent yields (80–99%). In addition, a gram-scale reaction and further application of the reaction strategy were performed.
Copper(II) complexes derived from furfurylamine and thiophenyl ligands: cytotoxicity, antioxidant properties, and molecular docking assessments
Back, Davi Fernando,Chaves, Otávio Augusto,Fontana, Liniquer André,Iglesias, Bernardo Almeida,Neves, Ademir,Oliveira, Pamella Schramm,Rossato, Aline,Sagrillo, Michele Rorato,Siqueira, Josiéli Demetrio,da Silva Fernandes, Liana,de Pellegrin, Sidnei Flores
supporting information, (2021/12/20)
This manuscript describes the synthesis, structural analysis, antioxidant evaluation, cytotoxicity, interaction with DNA, and molecular docking modeling of copper(II) complexes derived from aromatic aldehydes and amines containing furyl and thiophene frag
Aromatic dialdehyde-based bisbenzoxazines: The influence of relative position of oxazine rings
Tavernier, Romain,Granado, Lérys,Foyer, Gabriel,David, Ghislain,Caillol, Sylvain
, (2020/12/09)
Polybenzoxazines are known to have superior thermal stability. Especially, the use of aromatic aldehydes instead of formaldehyde for the synthesis of benzoxazines monomers could improve this stability. However, the increase in aromatic content of the mono
Synthesis and spectral studies on Ni(II) complexes involving N-furfuryl-N-substituted benzyldithiocarbamates and PPh3: Anagostic and C–H…π(chelate) interactions in (N-furfuryl-N-(4-fluorobenzyl)dithiocarbamato-S,S′)(thiocyanato-N)(tr
Sathiyaraj,Thirumaran,Ciattini, Samuele
, p. 1042 - 1050 (2016/07/06)
Twelve new nickel(II) complexes of functionalized dithiocarabamates [Ni(S2CNRR?)2](1-6) and [Ni(S2CNRR?)(NCS)(PPh3)](7-12) [where R=furfuryl; R?=2-hydroxy benzyl (1,7), 3-hydroxy benzyl (2,8), 4-hydroxy benzyl (3,9), 4-methoxy benzyl
Synthesis and solid state structures of two new copper(II) complexes of Schiff bases derived from furfuryl and tetrahydrofurfurylamine
Chen,Miao,Li,Zhu,Zeng
, p. 929 - 933 (2014/07/08)
Two Schiff base copper(II) complexes, bis(N-furfurylsalicylaldiminato) copper(II) (I) and bis(N-tetrahydrofurfurylsalicylaldiminato)copper(II) (II), were synthesized and their solid state structures were determined by X-ray crystallography. Complex I has
Intra-molecular Diels-Alder reactions of citraconamic acids from furfurylamines and citraconic anhydride: Effects of substitution in the furan ring on regioselectivity
Murali, Rajappa,Surya Prakash Rao,Scheeren, Hans W
, p. 3165 - 3174 (2007/10/03)
Regioselectivity in the intra-molecular Diels-Alder (IMDA) reaction of furfurylcitraconamic acids derived from N-benzylfurfurylamines and citraconic anhydride can be controlled by substituents located in the furan ring and by reaction conditions. Reactions conducted under kinetic conditions resulted in cycloaddition products having methyl and aminomethylene substituent in 1,3-relationship whereas under thermodynamic conditions, excepting in the case of the 3-methylsulfanyl group, the products rearranged to more stable cycloadducts in which the substituents are in 1,2-relationship. Product formation can be explained on the basis of frontier orbital interactions and steric considerations.
Synthesis and Reactions of Coumarin-3-N-bromoarylcarboxamides
Islam, A. M.,Bedair, A. H.,Aly, F. M.,El-Sharief, A. M. Sh.,El-Masry, F. M.
, p. 224 - 226 (2007/10/02)
Various coumarin-3-N-bromoarylcarboxamides (Ia-h) have been prepared and their reactions with aliphatic amines and hydrazines studied.Some acridinyl derivatives (XIa-f) of coumarin-3-carboxamide (Ii) have also been prepared.
