76154-06-8

Basic information

• Product Name: N-phenyl-(1-(4-methylphenyl)ethylidene)amine
• Synonyms: N-phenyl-(1-(4-methylphenyl)ethylidene)amine
• CAS NO: 76154-06-8
• Molecular Weight: 209.291
• Mol File: 76154-06-8.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: N-phenyl-(1-(4-methylphenyl)ethylidene)amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenyl-(1-(4-methylphenyl)ethylidene)amine(76154-06-8)
• EPA Substance Registry System: N-phenyl-(1-(4-methylphenyl)ethylidene)amine(76154-06-8)

Safety Data

• Hazardous Substances Data: 76154-06-8(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 766-97-2 4-n-methylphenylacetylene 
• 122-00-9 para-methylacetophenone 
• 4209-16-9 N-phenyl-1-(p-tolyl)ethan-1-imine 

Downstream Products

• 1086215-15-7 Phenyl-[1-p-tolyl-eth-(Z)-ylidene]-amine 
• 344876-68-2 C₂₁H₁₈N₂ 
• 145473-87-6 1-(4-methylphenyl)-1-phenyl-2-propanone 
• 91118-57-9 2-(4-methylphenyl)-1,4-diphenyl-1,4-diazabutadiene N⁴-oxide 
• 92645-93-7 N-phenyl-1-(4-methylphenyl)ethylamine 

Relevant articles and documents

Ruthenium N-Heterocyclic Carbene Complexes for Chemoselective Reduction of Imines and Reductive Amination of Aldehydes and Ketones

Chemoselective reduction of imines to secondary amines is catalyzed efficiently by tethered and untethered, half-sandwich ruthenium N-heterocyclic carbene (NHC) complexes at room temperature. The untethered Ru-NHC complexes are more efficient as catalysts for the reduction of aldimines and ketimines than the tethered complexes. Using the best untethered complex as a catalyst, electronic and steric demands on the reaction was probed using a series of imines. Chemoselectivity of the catalyst towards imine reduction was tested by performing inter and intramolecular competitive reactions in a variety of ways. The catalyst exhibits a very high TON and TOF under anaerobic conditions.

Heterogeneous intermolecular hydroamination of terminal alkynes with aromatic amines

Heterogeneous intermolecular hydroamination of alkynes with aromatic amines using inexpensive transition metal-exchanged clay catalysts was investigated. Reaction of terminal alkynes with aromatic amines gave higher yields of imines.

Well-defined chiral spiro iridium/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure

New chiral phosphine-oxazoline ligands (7, SIPHOX) with a rigid and bulky spirobiindane scaffold were synthesized, starting with optically pure 7-diphenylphosphino-7′-trifluoromethanesulfonyloxyl-1,1′- spirobiindane, in four steps in 40-64% overall yield.