76184-41-3Relevant academic research and scientific papers
SYNTHESIS OF A CHIRAL 1,1,3-TRIMETHYLCYCLOHEXANE DERIVATIVE FROM d-CAMPHOR: A POTENT KEY BUILDING BLOCK FOR ENT-TAXANE-TYPE DITERPENOIDS
Kitagawa, Isao,Shibuya, Hirotaka,Fujioka, Hiromichi,Kajiwara, Akiharu,Tsujii, Shinji,Yamamoto, Yoshio
, p. 1001 - 1004 (2007/10/02)
A chiral 1,1,3-trimethylcyclohexane derivative (12), which is a potent key building block for synthesis of ent-taxane-type diterpenoids, has been prepared from d-camphor (2) through a conversion pathway which involves a novel ring enlargement reaction of a 1,1,2-trimethylcyclopentane derivative (3).
