76185-65-4Relevant articles and documents
The molecular structures and electrochemical response of "twisted" tetra(aryl)benzidenes
Low, Paul J.,Paterson, Michael A. J.,Goeta, Andres E.,Yufit, Dmitry S.,Howard, Judith A. K.,Cherryman, Julian C.,Tackley, Daniel R.,Brown, Bev
, p. 2516 - 2523 (2004)
The compounds N,N,N′,N′-tetra(4-methylphenyl)-(1,1′- biphenyl)-4,4′-diamine (4), N,N,N′,N′-tetra(4-methylphenyl)- (2,2′-dimethyl)-(1,1′-biphenyl)-4,4′-diamine (5a) and N,N,N′,N′-tetra(4-methylphenyl)-(2,2′,6,6′-tetramethyl) -(1,1′-biphenyl)-4,4′-diamine (
Metal-Free Oxidative C-C Coupling of Arylamines Using a Quinone-Based Organic Oxidant
Maddala, Sudhakar,Mallick, Sudesh,Venkatakrishnan, Parthasarathy
, p. 8958 - 8972 (2017/09/11)
A variety of arylamines are shown to undergo oxidative C-C bond formation using quinone-based chloranil/H+ reagent as the recyclable organic (metal-free) oxidant system to afford benzidines/naphthidines. Arylamines (3°/2°) designed with various substituents were employed to understand the steric as well as electronic preferences of oxidative dimerization, and a mechanism involving amine radical cation has been proposed. The tetraphenylbenzidine derivative obtained via oxidative C-C coupling has been further converted to blue-emissive hole-transporting material via a simple chemical transformation. This study highlights the preparation of novel HTMs in a simple, economic, and efficient manner.
Oxidative Dimerization of Triarylamines Promoted by WCl6, Including the Solid State Isolation and the Crystallographic Characterization of a Triphenylammonium Salt
Bortoluzzi, Marco,Marchetti, Fabio,Pampaloni, Guido,Pinzino, Calogero,Zacchini, Stefano
, p. 887 - 893 (2016/02/03)
The triphenylammonium salt [NHPh3][WCl6], 1, and the product of the C-C dimerization of triphenylamine, Ph2N(C6H4)2NPh2, 2, were afforded from the reaction between WCl6 and NPh3 in CH2Cl2. Compound 2 was isolated in 43% yield upon hydrolysis of the reaction mixture. The X-ray structure of 1 provides the first crystallographic characterization of the triphenylammonium ion. Combined EPR and DFT studies gave insight into the reaction mechanism, and allowed the identification of WCl5···[Cl(C6H4)NPh2] as a presumable key intermediate. The reactions of WCl6 with 4-bromotriphenylamine, 4,4′-dimethyltriphenylamine, 9-phenylcarbazole, followed by hydrolytic treatment, led to the dimerization products 3-6, in admixture with variable amounts of the parent amines. N,N,N′,N′-tetrakis(4-bromophenyl)-[1,1′-biphenyl]-4,4′-diamine, 3, was isolated in 60% yield from the reaction of WCl6 with 4,4′-dibromotriphenylamine.