762-13-0 Usage
General Description
bis(1-oxononyl) peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. bis(1-oxononyl) peroxide is generally stored or transported as a mixture, with an inert solid.
Reactivity Profile
Peroxides, such as bis(1-oxononyl) peroxide , are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. Solutions of peroxides often become explosive when evaporated to dryness or near-dryness. Danger of explosion when dry. May explode from heat, contamination or loss of temperature control. These materials are particularly sensitive to temperature rises.
Safety Profile
A peroxide. Handle
with care. When heated to decomposition it
emits acrid smoke and irritating vapors.
Check Digit Verification of cas no
The CAS Registry Mumber 762-13-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 7,6 and 2 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 762-13:
(5*7)+(4*6)+(3*2)+(2*1)+(1*3)=70
70 % 10 = 0
So 762-13-0 is a valid CAS Registry Number.
InChI:InChI=1/C18H34O4/c1-3-5-7-9-11-13-15-17(19)21-22-18(20)16-14-12-10-8-6-4-2/h3-16H2,1-2H3
762-13-0Relevant articles and documents
Iron-Catalyzed Regioselective Decarboxylative Alkylation of Coumarins and Chromones with Alkyl Diacyl Peroxides
Jin, Can,Sun, Bin,Xu, Tengwei,Yan, Zhiyang,Zhang, Xun
supporting information, p. 1585 - 1591 (2019/08/07)
A facile iron-catalyzed decarboxylative radical coupling of alkyl diacyl peroxides with coumarins or chromones has been developed, affording a highly efficient approach to synthesize a variety of α-alkylated coumarins and β-alkylated chromones. The reaction proceeded smoothly without adding any ligand or additive and provided the corresponding products containing a wide scope of functional groups in moderate to excellent yields. This protocol was highlighted by its high regioselectivity, readily available starting materials, and operational simplicity.
