76202-64-7

Upstream product

• 21400-41-9 1,1,2,4,4-pentachloro-1,3-butadiene 
• 18803-44-6 sodium p-chlorothiophenolate 
• 77301-83-8 1,2-Dichlor-1,4,4-tris(4-chlor-phenylthio)-1,3-butadien 
• 106-54-7 p-Chlorothiophenol 
• 62897-26-1 tetrakis(4-chlor-phenylthio)butatrien 

Downstream Products

• 62897-26-1 tetrakis(4-chlor-phenylthio)butatrien 
• 76202-66-9 2,3-Dichlor-1,1,4,4-tetrakis(4-chlor-phenylthio)-1,3-butadien 
• 76211-87-5 2,3-Diiod-1,1,4,4-tetrakis(4-chlorphenylthio)-1,3-butadien 
• 76202-59-0 2,3-Dibrom-1,1,4,4-tetrakis(4-chlorphenylthio)-1,3-butadien 
• 76202-65-8 2-Brom-1,1,4,4-tetrakis(4-chlorphenylthio)-1,3-butadien 
• 72485-86-0 2-Chlor-1,1,3,4,4-pentakis(4-chlor-phenylthio)-1,3-butadien 

Relevant academic research and scientific papers

Thio-substituted Butynes and Butadienes from Polychlorobutenes and Thiols

Hexachlorobutene (1) yields compounds 2 - 4 with thiolates in water-containing ethanol solutions at room temperature.Reaction of 2b with potassium tert-butoxide yields compound 5b.The tris(arylthio) derivative 4b is formed by reaction of 3b with sodium 4-

Reactions of Polychloro-1,3-butadienes and Polychlorobutenes with Thiolates

On treatment of perchlorobutadiene (1), of the pentachlorobutadienes 10 and 18, or of the hexachlorobutenes 21, 25, and 32 with thiolates in DMSO a very fast and extensive replacement of chlorine is observed even at room temperature.The reactions 1 -> 7,

Reactions of Poly(organylthio)butenynes and -butatrienes with Electrophilic Reagents

Starting from the poly(organylthio)substituted butenynes 1 and the butatrienes 2 or 5 the butadiene derivatives 3, 4, 6, 7 and 8 are obtained by addition of halogens, hydrogen halides or 4-chlorophenylsulfenyl chloride.The chlorine addition products 3, no