76217-04-4Relevant academic research and scientific papers
Palladium-catalyzed preparation of exo-aryl derivatives of the norbornane skeleton
Arcadi, A.,Marinelli, F.,Bernocchi, E.,Cacchi, S.,Ortar, G.
, p. 249 - 256 (1989)
Norbornene and norbornadiene derivatives have been shown to react with aryl and vinyl halides in the presence of a palladium catalyst, formic acid, and tributylamine or piperidine to give hydroarylated and hydrovinylated derivatives in good to high yield.Extension of the reaction to the hindered α,β-unsaturated aldehydic system of myrtenal produced a monocyclic derivative through a palladium-catalyzed ring opening.
Stille cross-couplings of unactivated secondary alkyl halides using monoorganotin reagents
Powell, David A.,Maki, Toshihide,Fu, Gregory C.
, p. 510 - 511 (2007/10/03)
The first catalyst that achieves Stille cross-couplings of secondary (as well as primary) alkyl halides has been developed. The method employs easily handled and inexpensive catalyst components (NiCl2 and 2,2′-bipyridine) and, through the use of monoorganotin reagents, avoids the formation of toxic and difficult-to-remove triorganotin side products. Copyright
