76232-43-4Relevant academic research and scientific papers
New C-C bond formation through the nickel-catalysed electrochemical coupling of 1,3-enynes and carbon dioxide
Derien, Sylvie,Clinet, Jean-Claude,Dunach, Elisabet,Perichon, Jacques
, p. 213 - 224 (2007/10/02)
A series of 1,3-enynes has been carboxylated in a nickel-catalysed electrochemical reaction carried out in a single-compartment cell fitted with a consumable magnesium anode.When 2,2'-bipyridine (bipy) or pentamethyldiethylene triamine (PMDTA) are added a
Palladium-Catalyzed Synthesis of 2,4-Dienoic Acid Derivatives from Vinylic Halides
Kim, Jin-Il,Patel, Babu A.,Heck, Richard F.
, p. 1067 - 1073 (2007/10/02)
A wide variety of vinylic bromides and iodides have been coupled with acrylic, methacrylic, crotonic, and maleic esters and in some cases with the free acids, nitriles, and amides.In general, good yields of the 2,4-dienoic acid derivatives were obtained.The stereochemistry of the products was determined and the factors influencing the stereoselec-tivity of the reaction were studied.
