76236-83-4Relevant academic research and scientific papers
STEREOCHEMISTRY OF DIHYDROPINOL AND 1,8-CINEOL DERIVATIVES. PART IV. ISOMERIC EPOXYALCOHOLS AND GLYCOLS FROM THE DIHYDROPINOL SYSTEM
Mrozinska, Danuta,Piatkowski, Krzysztof
, p. 693 - 702 (2007/10/02)
Hydroboration-oxidation and epoxidation reactions of (+/-)-endo-2-hydroxy-2,6,6-trimethyl-7-oxabicyclooctene-3 ((+/-)-1-hydroxy-cis-2,3-pinol) were carried out. (+/-)-endo-3,4-Epoxy-endo-2-hydroxy-2,6,6-trimethyl-7-oxabicyclooctane ((+/-)-1-hydroxy-trans-2,3-epoxy-cis-dihydropinol) resulting from epoxidation was starting material for obtaining stereoisomeric glycols.Epoxidation of (+/-)-endo-3-hydroxy-2-methylen-6,6-dimethyl-7-oxabicyclooctene-2(9) ((+/-)-trans-2-hydroxy-1,7-pinol) was also carried out producing both stereoisomeric epoxyalcohols.
