76263-55-3

Basic information

• Product Name: Benzene, 2-iodo-4-nitro-1-(4-nitrophenoxy)-
• CAS NO: 76263-55-3
• Molecular Formula: C12H7IN2O5
• Molecular Weight: 386.102
• Mol File: 76263-55-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 2-iodo-4-nitro-1-(4-nitrophenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 2-iodo-4-nitro-1-(4-nitrophenoxy)-(76263-55-3)
• EPA Substance Registry System: Benzene, 2-iodo-4-nitro-1-(4-nitrophenoxy)-(76263-55-3)

Safety Data

• Hazardous Substances Data: 76263-55-3(Hazardous Substances Data)

Upstream product

• 19169-99-4 (4-nitrophenyl)-λ3-iodanediyl diacetate 
• 89487-91-2 2-iodo-4-nitrophenol 

Downstream Products

• 101-80-4 4,4'-oxydiphenylene diamine 

Relevant articles and documents

Synthesis of medium-sized (6-7-6) ring compounds by iron-catalyzed dehydrogenative C-H activation/annulation

In this report, we have described a FeCl3-catalyzed process involving intramolecular annulation of o-phenoxy diarylacetylenes via hydroarylation to afford a series of biologically potent fused seven-membered (6-7-6) ring compounds under mild reaction conditions. This reaction was believed to proceed through Friedel-Crafts type sequential carbometallation followed by protonation to produce phenyldibenz[b,f]oxepines. This method was also extended to synthesize seven-membered rings that are fused with coumarins.