76270-92-3Relevant academic research and scientific papers
A comparison of the rates of alkyl migration in the complexes (M = Fe, Ru, Os; Cp = η5-C5H5)
George, Robyn,Andersen, Jo-Ann M.,Moss, John R.
, p. 131 - 134 (1995)
The rates of alkyl migration for selected members of the series (M = Fe, Ru, Os; Cp = η5-C5H5; R = CH3 to n-C18H37) show dependence on both the alkyl group and the metal.Keywords: Iron; Ruthenium; Osmium; Cyclopentadienyl; Alkyl migration; Carbonyl
Carbon-Oxygen and Carbon-Hydrogen Bond Cleavage in the Reaction of 2>+ with Phosphite and Phosphine Ligands
Howell, James A. S.,Rowan, Anthony J.
, p. 1845 - 1851 (2007/10/02)
Reaction of 2> (cp=η5-cyclopentadienyl) with P(OR)3 ligands (R=Me, Et, or Bun) yields , 2>, and > complexes resulting from C-O bond cleavage.The former complexes were characterized by reaction with PPh3 which yields the acyl derivative.Reaction of 2> with PPr3 and PMe2Ph proceeds to yield a mixture of the substituted dimer and the hydrides (x=0 or 1) depending on the reaction conditions.The mechanisms of these reactions and the fluxionality of the substituted dimers are discussed.
