76295-13-1Relevant academic research and scientific papers
The Kinetics and Mechanism of Substitution of Chloride Ion in Trans-Cl by Parahydroxy Benzoic Acid
Ghoshal, Amalendu,Siddhanta, S. K.
, p. 443 - 446 (2007/10/02)
The steric course of the Cl(-) ion substitution in trans-(+) by p-hydroxy benzoate ion was studied in 15percent (v/v) ethanol at pH 3 and at 30 degC.A mechanism has been proposed.Convincing proof for the proposed mechanism was obtained by comparing the spectrophotometrically obtained values of concentration of the different species at different times (during the course of the reaction) with the corresponding values calculated using the rate constants.The rate constants were determined by a combination of potentiometric and spectrophotometric metods and studyind the reaction part by part.
