76313-27-4Relevant academic research and scientific papers
Phosphinites of Carbohydrates as Chiral Ligands for Asymmetric Synthesis Catalysed by Complexes. IV. - Influence of the Solvent and the Structure of Cationic 4,6-O-Benzylidene-2,3-O-bis(diphenylphosphino)-D-hexopyranoside-rhodium(I) Chelates on Enantiosel
Selke, Ruediger
, p. 717 - 724 (2007/10/02)
Cationic rhodium(I)-chelates of 4,6-benzylidene-2,3-O-bis(diphenylphosphino)-D-hexopyranosides bearing axial O-functions, as for instance manno- 5 and galactopyranosides 4c, 4d or α-D-glycopyranosides, show lower enantioselectivity in the hydrogenation of
